High-Density Polyethylene, usually shortened to HDPE or PEHD, is a plastic polymer with flexible properties which make it ideal for a wide range of applications.
High-density polyethylene, as the name suggests, has a higher specific density than low-density polyethylene, though this difference is only marginal. What really makes the difference in the physical properties of HDPE is the lack of branching, meaning it is light with a high tensile strength. Because there is no branching the structure is more closely packed, make HDPE a linear polymer. The branching can be controlled and reduced by using specific catalysts during production.
Properties and Applications of HDPE
HDPE has many advantageous properties that make it important in the manufacturing of different products. HDPE has a comparatively high density compared to other polymers, with a specific gravity of 0.95. HDPE is relatively hard and resistant to impact and can be subjected to temperatures of up to 120
oC without being affected.
HDPE is not autoclavable, unlike Polypropylene (PP). Autoclaving conditions are used to sterilise products using high pressures and temperatures. For more information regarding PP, please read the following article:
HDPE is recognisable by its opaque or translucent appearance.
These durable properties make it perfect for heavy duty containers and HDPE is primarily used for milk containers, as well as Tupperware, shampoo bottles, bleach bottles and motor oil bottles. Also, HDPE does not absorb liquid readily, making it good barrier material for liquid containers. Almost a third (about eight million tons) of HDPE produced worldwide is used for these types of containers.
Furthermore HDPE is an extremely resistant material to many chemicals, hence it widespread use in healthcare and laboratory environments. It is resistant to many acids, alcohols, aldehydes, esters, bases and oils.
Other uses for HDPE include:
Plastic shopping bags
Food containers (HDPE is approved for contact with food by many food advisory boards)
A typical container constructed from HDPE. Image Credit: http://web.ncifcrf.gov/ Recycling of HDPE
HDPE is accepted at most recycling centres in the world, as it is one of the easiest plastic polymers to recycle. Most recycling companies will collect HDPE products and take these to large facilities to be processed.
First, the plastic is sorted and cleaned, to remove any unwanted debris. The plastic then needs to homogenised, so that only HDPE will be processed. If there are other plastic polymers in the batch, this can ruin the recycled end-product.
HDPE has a specific density of 0.93 to 0.97 g/cm
3. This is much lower than that of PET which is 1.43-1.45 g/cm 3, meaning that these plastic polymers can be separated by using sink-float separation. However, HDPE has a similar specific density to PP, which means the sink-float separation cannot be used. In this case, Near Infrared Radiation (NIR) techniques can be used, unless the plastic is too dark and absorbs the infrared waves.
HDPE is then shredded and melted down to further refine the polymer. The plastic is then cooled into pellets which can be used in manufacturing.
Recycling plants can also benefit from the use of a baler, which can compress the post-consumer waste to minimise energy used in transport.
Small steps at home can also be taken to recycle HDPE. With regards to milk bottles, these can easily be reused if washed out thoroughly first. To reduce packaging waste, buying plastic bottles in bulk is another good option.
Equally, carrier bags can also be reused when going shopping. Many large supermarkets also offer collection points for used carrier bags to be recycled. Some plastic films contain a message to recycle these with carrier bags at the supermarket and not to leave ‘kerbside’.
Recycling of HDPE is aided by the resin code on the product, which is an indiscriminate number assigned to different plastic polymers to help separate plastics at the recycling stage. The resin identification code for high-density polyethylene is ‘2’.
The Environmental Benefits of Recycling HDPE
The worldwide market for HDPE is huge, with a market volume of around 30million tons per year.
The amount of plastic used in plastic bags has reduced by around 70% in the last 20 years thanks to the introduction of reusable canvas bags and using biodegradable materials, but the majority of bags are still produced from HDPE. Furthermore, there is a growing market for HDPE containers in China and India due to increased standards of living, as well as a higher demand for HDPE pipes and cables due to rapidly growing industries.
HDPE is non-biodegradable and can take centuries to decompose, so it is imperative that these bags and containers are recycled and used again.
Recycling HDPE has many benefits. For example, it is more cost efficient to produce a product from recycled HDPE than it is to manufacture ‘virgin’ plastic.
HDPE, like many plastic polymers, is produced using considerable amounts of fossil fuels and it takes a total of 1.75kg of oil to manufacture just 1kg of HDPE.
Many new products can be manufactured using recycled HDPE, including: